Thursday, September 1, 2016

Six side Sealing of stone – Breaking myths of Debonding



Six side Sealing of stone – Breaking myths of Debonding

For years the use of sealers has been expressly for the protection of the stone or tile surface. Most, if not all, adhesive companies warranty their adhesives only if the back of the stone is free from any sealer as sealers are seen as “bond breakers” adversely affecting the integrity of the adhesives ability to bond to the stone or tile surface. However this situation has meant that many of the problems created by water absorption through the back and the sides of stone have gone unresolved. New and current technology now offers sealers that can successfully be applied to the bonded surfaces of stone without becoming bond breakers. To look at these and how they work I firstly want to investigate the problems and issues relating to porous stone and specifically water absorption through the sides and back.

Picture framing, efflorescence, soluble mineral contamination (for example iron Sulphides such as Pyrite) and prolonged water marking are some of the problems created when water is absorbed by the back and sides of some types of stone. The mechanics are as follows. When a stone is installed over a concrete substrate the concrete can contain potential soluble contaminants such as salts and other minerals. The underlying cement based screed or topping as well as the cement based adhesive and grout also have the potential to hold some of these contaminants. In most cases the contaminants will not react unless there is water present. Water is both the catalyst as well as the transport mechanism. The initial and most important source of water that triggers much of the reaction originates from the hydrating adhesive or mortar bed that is even more aggressive due to its high ph. With water the soluble minerals travel to the surface by way of evaporation and capillary action working their way through the stone and grout. In many cases the grout is more porous having higher water absorption than the stone creating an easier exit for the evaporating soluble minerals. This explains why in many cases the resulting stains are revealed as picture framing or at least concentrated around the sides of the stone and grout joint. Once on or near the surface the contaminants further react with the increasing rate of oxygen and ambient air temperature to form various compounds or simply evaporate or dissolve only partially leaving behind the unwanted stain or compound.



A good example of this mechanism at work is the soluble iron salts found in the granites and marbles across various projects.

The water from the thick mortar bed under the stone once absorbed into the stone body easily reacted with the soluble salts to form highly visible iron blooms. In some cases the iron salts would turn the complete stone a light shade of yellow. The solution to this problem is simple – if the stone’s natural water absorption could be reduced close to zero then the risk of iron contamination would be similarly reduced. The best and most cost effective way to reduce the stones water absorption is to seal the stone on all six sides. 

We have all known for many years that the trick to managing many of the water related problems of soluble mineral staining such as the iron salts is to lower the stones natural water absorption by sealing it on all six sides while still maintaining good vapor transmission. (The ability for the sealer to breath is very important as any trapped water can create other issues such as surface debonding by way of excessive moisture expansion. However the formation of the contaminants is not only due to the presence of water but also the quantity of water and rate of evaporation. If the amount of water is reduced and the rate of evaporation high enough that the water does not condense then the soluble minerals will also exhaust through the surface rather than solidify ). The problem however is that most sealers either did a poor job of repelling water in a high alkaline environment as that found at the interface between stone and cement mortar, or reduced the bond strength of the adhesive system. The latter is the reason why most adhesive manufacturers only warranted their adhesives when applied to clean unsealed stone. This claim in turn made clients reject any sealer solution to the problem as well as making sealer manufacturers uninterested in developing specific sealer technology. However as stone’s use increased globally so did the problems related to the high water absorption and chemistry of certain stones. All of this at last led to the development of sealers that could in fact both reduce a stone’s water absorption as well as maintaining the adhesive’s bond.

RachTR has designed the sealer specifically for application to the back and sides of stone called RachTR Back Seal. It is designed to hit the main market requirements for such a product – low cost per m2 (or sq ft), highly water repellent, good vapour transmission and of course not being a bond breaker for the adhesive. However we realized that the best way to apply sealers to the sides and back in a cost effective manner was to dip the entire stone. However this presented a problem in that many clients wanted a low cost sealer for the back and sides such as RachTR Back Seal but wanted a premium product for the actual surface, which would be exposed to long-term dirt and contamination. Therefore any specialized back applied sealer had not only to be compatible with a premium sealer but also needed to allow the premium sealer to penetrate it so the correct quantity of premium sealer could be applied to the surface. RachTR Top Seal is designed to satisfy both these conditions. The sub surface sealers will penetrate right through the RachTR Back Seal enabling the complete and correct quantity of premium sealer to be applied guaranteeing the long term performance of the final sealer.

Both of these sealers are tested regarding shear bond to ensure they do not act as bond breakers.

The contemporary existence of sealers that can be applied to the sides and back of a stone or tile now help to manage and greatly reduce the risk of the long endured problems created by moisture moving through the stone especially during installation and the process of final cure. The argument by both clients and adhesive manufacturers to not seal all sides due to the possibility of the sealer being a bond breaker is no longer valid now the technology exits to do so. 

Using a suitable sealer on all six sides is part of a total water management system that should be implemented to fully control the uses around leaching of soluble minerals. These include for example the use, where appropriate, of waterproof membranes, epoxy remediation systems, proper falls, factory prepared adhesives and grouts etc.

Wednesday, August 17, 2016

CEMENT vs ADHESIVES – A COMPARISON




CEMENT vs ADHESIVES – A COMPARISON

Cement is a fine, grey powder that is used as a construction binding material. When mixed with water, cement reacts chemically and becomes hard and strong. Cement is categorized as either hydraulic or non-hydraulic, depending on how it mixes with water.

Non-hydraulic cement does not harden underwater or in damp conditions. Certain chemicals are added to make hydraulic cement, which sets underwater or in wet conditions.

Cement is made by combining silicon, aluminum, iron, calcium and other chemicals in a controlled mixture. Other materials added to the mixture include chalk, clay, slate and limestone. 

When combined, the ingredients form a hard substance that is ground into cement. It is mixed with water to form mortar or mixed with sand, gravel, and water to make concrete.

White Cement, Difference between Grey and White Cement:

White cement is largely used to increase the aesthetic value of a construction. It is a kind of Ordinary Portland Cement inclusive of clinker, fuel oil and iron oxide. The content of iron oxide is maintained below 0.4% to secure whiteness. White Cement and Grey Cement are usually compared on five terms which are as follows:

1. Raw Material: Grey colour of the cement is mainly due to high content of oxides of iron, manganese and chromium which are present in limited amount in white cement.

2. Strength and Setting Time: Its setting behavior and strength development are essentially the same as those expected in grey cement.

3. Fineness: White cement is usually finer than grey cement and thus, gives better finishing.

4. Cost: Due to more complex manufacturing process of white cement, it is expensive than grey cement. In India, white cement is usually costlier than grey cement.

5. Uses: White cement due to its whiteness is mainly used for architectural beauty, interior and exterior decorations, flooring, ornamental concrete products such as idols while grey cement are mostly used for construction purposes.

Cement Properties

Curing Time

Curing plays an important role on strength development and durability of concrete and takes place immediately after concrete placing and finishing.

It involves maintenance of desired moisture and temperature conditions, both at depth and near the surface, for extended periods of time. Properly cured concrete has an adequate amount of moisture for continued hydration and development of strength, volume stability, resistance to freezing and thawing, and abrasion and scaling resistance. 

Effect of curing duration on compressive strength development is presented in Figure 


Compressive strength

Compressive strength test is carried out to ascertain quality of cement when used for important structures. Strength test is not made on plain cement due to excess shrinkage and cracking of plain cement paste and is carried out either on cube or cylinder.

Compressive strength of concrete depends on many factors such as water-cement ratio, cement strength, quality of concrete material, and quality control during production of concrete etc.

Various standard codes recommend concrete cylinder or concrete cube as the standard specimen for the test. 

Compressive Strength = P/A
Where,

 P=Maximum load applied to the cube. (N)
 A=Cross sectional area (Calculated from the     mean dimensions) (mm2)

Tensile strength

Cement is very weak in tensile strength. Its strength is determined directly using the briquettes.

Tensile Strength = P/A
Where,

P=Maximum load applied to the cube. (N)
A=Cross sectional area (Calculated from the mean dimensions) (mm2)

Flexural Strength

Flexural strength is one measure of the tensile strength of concrete. It is a measure of an unreinforced concrete beam or slab to resist failure in bending.

It is measured by loading 6 x 6 inch (150 x 150-mm) concrete beams with a span length at least three times the depth.

The flexural strength is expressed as Modulus of Rupture (MR) in psi (MPa) and is determined by standard test methods ASTM C 78 (third-point loading) or ASTM C 293 (center-point loading).

fr = bfcn 

Where fc is the compressive strength of the concrete b (varies from 0.33 to 0.94)
n (1/2 or 2/3) are coefficients which depend on factors such as strength levels, aggregate properties and mineralogy, admixtures types, moisture content of specimen, compaction and curing conditions, specimen geometry and confinement, age of concrete, etc.

The value reported for the flexural tensile strength by various investigators and standards in square root form (n = 1/2) ranges from 0.3 to 1.0 fc0.5 MPa 

Shear Bond Strength

Shear bond strength of a adhesive is the shear force required to debond a known area of two porcelain tiles and of two wall tiles, respectively, joined at their fair faces with an adhesive. 

The pieces used in testing consists of two fragments of tile, measuring about 6,8 x 4,8 cm, stuck together at their fair faces with the adhesive tape, the contact area being about 5,0 x 4,8 cm. The force was applied using a steel wedge with a 1-mm-thick flat edge that rested on one of the tile fragments, as close as possible to the side where the adhesive was applied. The tests were performed in a universal testing machine at a speed of 0, 5 mm/min. 
Shear bond strength was expressed as follows: 

σ= A. Fmax (1) 
A= e⋅b (2) 

Where,
F max = Maximum force (N) 
A = Contact area (mm2)
b = Piece width (mm) 
e = Height of the fitted fragment (mm) 
σ= Shear bond strength (N/mm2) 




Construction Adhesives

Construction adhesives are used to bond common materials used in the construction, renovation and finishing of homes by replacing traditional adhesives or fixings like cement, wood glues, nails and screws.

They are created by mixing the base material with fillers, pigments, stabilizers, plasticizers and other additives.

Low performance products are based on natural substances like starch protein or synthetic polymers like polyvinyl alcohol, acrylics, etc.

High performance products are based on polymers like epoxy, silicone, etc. and have enhanced properties like bond strength, elongation capacity, durability and environmental resistance.

Types of Adhesives

Along with cement, other adhesives to be considered are:

Unsaturated Polyester resin based Adhesive (UPR)

The polyester resin-based adhesives can be divided into two distinctive groups: saturated thermoplastic and unsaturated thermosetting resins.

Unsaturated polyester based adhesives usually involve the reaction between a dibasic acid or an anhydride and a diol. Without special catalysts, they cure only at elevated temperatures. 

They are mainly two-part systems that harden by the addition of a catalyst, usually peroxide such as methyl ethyl ketone peroxide or benzoyl peroxide (BPO).

They are widely used for glass fibre flooring, and automobile body repair. They find many applications in the construction industry as Mastic for Stones.

Epoxy Based Resin

Epoxies are one of the most versatile families of structural adhesives. They bond well with many substrates and can be easily modified to achieve a wide range of properties. They provide high shear strength on a wide variety of plastics, metals and glass.

When fully cured, these thermosetting adhesives offer high thermal and chemical resistance, as well as high cohesive strength and minimal shrinkage. 

The majority of epoxy adhesives contain diglycidyl ether of bisphenol A (DGEBA) as the main base epoxy resin. Other epoxy resins are also used but to a much lesser extend due to their (much) higher price. 

Modified Cement based Adhesive or Tile Adhesives or Thin Set Adhesives

Cement-based, polymer modified adhesives are suitable for fixing a variety of ceramic tiles, mosaics, quarries, natural stone, marble and terrazzo in interior and exterior situations also known as tile adhesives. 

Suitable for walls and floors. May also be used for the installation of rigid foam insulating materials, for external walls.

Thin set Mortar adhesives, also known as tile adhesives or tile glue or marble glue, are used for tile & marble flooring. They can be used to install tiles in wet areas or areas subjected to frequent heat. 

They have a stronger, more flexible bond and ability to support a lot of weight and hence used for flooring. 

They are not come pre-mixed and need to be mixed with water or sometimes an acrylic additive if it’s not blended in already. For outdoor and wet mosaics, thin set is recommended instead of adhesives. 

Polyurethane based Adhesive (PU)

Polyurethane adhesives are one of the most important types of structural adhesives.
Their properties can be tailored over a wide range for a large number of applications. They can be rigid and hard or flexible and soft. They provide extremely strong bonding.

Even before the adhesive dries and seals completely, the initial bond is strong enough that clamps and other types of securing instruments are unnecessary. 
This makes manufacturing and construction processes both simpler and cheaper. 

Adhesive Usage Areas

Polyester adhesives bond well to glass, many plastics, and rubbers and to metal and wood. The adhesive bonds are resistant to water, gasoline, weak acids and many solvents. Unsaturated polyester adhesives are widely used for glass fiber laminates, optical products, furniture, concrete flooring and many applications in the construction industry.

PU adhesives bond exceptionally well to wooden substrates and find many uses in the wood industry. They have excellent low temperature properties but do not have high temperature resistance and decompose at much lower temperatures than epoxy adhesives. They do not bond well to metals unless a primer is applied to the substrate prior bonding.

Heavy duty construction adhesive
Heavy duty construction adhesive is ideal for a variety of surfaces, and can be used outside and indoors. 

Indoor construction adhesive

For interior projects using foam board, drywall, molding, paneling, plywood, masonry/concrete, corkboard or furring strips use an indoor construction adhesive.
For Tiles and Marbles - Tile Adhesives ares used for floor and walls. 

Extreme temperature subfloor & deck adhesive

An extreme temperature subfloor & deck adhesive actually increases the structural integrity of the wall, deck or subfloor, including plywood, OSB, particleboard, lumber and treated lumber.

Solid surface materials adhesive
To bond marble, granite, cultured and engineered stone to wood, drywall, painted surfaces, chipboard and concrete backer board use an adhesive designed specifically for the material. 

Tub surround & shower wall adhesives

Use a tub surround & shower wall adhesive to bond plastic, fiberglass and foam back tub and shower surrounds to drywall, cement backer board, ceramic tile, plywood or green board. 

Fiberglass reinforced plastic panel adhesives

The best way to adhere fiberglass reinforced plastic (FRP) panels to cured concrete, cement backer board, drywall, wood or green board is with an adhesive specifically designed for the panels.


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Website - www.rachtr.com,

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